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Coffee

Detailed Answers About Coffee

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By Arthur Tiersky

Coffee is one of those products that one can safely describe as having a cult following. Rabid, impassioned coffee-drinkers will find no shortage of comrades on the internet, and thus, an inexhaustible supply of tips, advice, and anecdotal evidence on every aspect of it imaginable, including the ideal means and duration of storage. To give you the most reliable advice, we’ve consulted food scientists and university websites for most of the information provided in our Q/As.

Though different sites give somewhat different advice, everyone DOES seem to agree on is that air and moisture are not coffee's friends. Therefore, your coffee beans should be stored in an air-tight container, such as a vacuum-sealed ceramic canister. Don’t use a glass one; everyone also agrees that light and heat are not kind to coffee.

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1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 4p 6 5s 2 4d 10 5p 6 6s 2 etc.

Introduction

The world of the atom is a very strange world. It is quite unlike the world we are used to. The usual relatively simple laws of physics do not apply. Instead the world of the atom is one dominated by waves

and probability. The speed and even the location of objects in this world are subject to uncertainty.

Electron Orbitals

Werner Heisenberg, one of the founders of Quantum Mechanics, was the first to describe this uncertainty mathematically. The Heisenberg Uncertainty Principle states that it is impossible to know with high levels of certainty both the location and the velocity of an electron. The better you know where an electron is, the worse your knowledge of where it is going.

The practical meaning of this is that the common picture given of atoms that looks like a solar system is not just a little inaccurate. It is dead wrong. Because of the uncertainty principle electrons cannot orbit in nice simple circles because if they did it would be possible to know their exact position and speed at any moment. Diagrams such as the one at right are useful for counting electrons and illustrating different energy levels. But they are worthless as pictures of what atoms really look like.

The solar system model of the atom uses orbits to show where the electrons are. Electrons do not really orbit the nucleus. They do live in regions of space called orbitals . Orbitals are organized by the energy level or shell that they belong to.

The uncertainty principle tells us that we cannot pin down the electron’s position exactly. Quantum physics calculations allow us to calculate the probability that an electron will be in a particular location. The combination of a large number of such calculations gives rise to a diagram like the clouds pictured on this page. The quantum physics equations reveal that in the lowest energy level the electrons can be found in a spherical region around the nucleus. Other orbitals have different shapes, as we will see. An orbital is the shape of the region in space where an electron is most likely to be found. At left you see what is called the 1s orbital. This ball-shaped orbital gives a better idea of what a hydrogen atom actually looks like. The dots in the picture represent possible positions of the one electron the hydrogen has. The nucleus (too small to see) is in the center of the picture. Notice that there are more dots near the center of the sphere than near the edges. This shows that the electron is most likely to be near the nucleus. But that does not mean it is impossible to find the electron very far away from the nucleus.

The next larger orbital in an atom is called the 2s orbital. It is one of the orbitals found in the second energy level (or shell) of an atom. The 2s orbital of an atom is shaped just like the 1s orbital except that it is larger than the 1s orbital. The 2s orbital is also different because it has two parts, an inner and outer sphere. An electron may be in either sphere but is never found in the border between them.

Generally, s orbitals all look alike but get bigger in higher energy levels. The same is true for the other types of orbitals: at higher energies they look similar but are bigger.

Orbitals and Energy

Electrons in atoms are organized into energy levels or shells. In the first shell electrons have the lowest possible potential energy within the atom. In the second shell electrons have higher potential energy. The shells have different types of orbitals within them, depending on their relative potential energy. Lower shells have fewer orbitals and higher shells have more orbitals. Each orbital can have either one or two of the atom’s electrons in it.

The electrons in an atom in the ground state all have a specific location. This location is given by the shell number and by the orbital. The diagram below shows how the orbitals are organized by their potential energy. In this activity you will learn how to determine where the electrons in atoms and ions are placed in such a diagram. You will also learn how to write a shorthand notation for such diagrams.

The energy levels or shells are distinguished by their number. This number is called the principal quantum number and is the most important quantum number for determining how much energy an electron has. This is also called the shell number and is an integer like 1, 2, or 3.

In each energy level the orbitals have specific names. For electrons with principal quantum number 1 there is only a 1s orbital. In the shell with principal quantum number 2 there are both a 2s orbital and three 2p orbitals. In the third shell there are one 3s, 3 3p, and 5 3d orbitals. The pattern continues this way and at each level a new type of orbital is added with letter-codes of f, g, h, i, etc. The original four letter-codes originate in spectroscopy in which scientists studied the lines in the emission spectrum of elements to learn about electron structure. They now do not have any relevant meaning but originally referred to features in the spectrum that were sharp, principal, diffuse, or fundamental.

Different orbitals have different shapes. The s-orbitals are all spherical and there is only one s-orbital in each shell. The p-orbitals all look like barbells made out of balloons and there are always three p-orbitals per shell. Each p-orbital points in a direction perpendicular to the others (p_x, p_y, p_z). Most of the d-orbitals look like various combinations of four balloons. There are always five d-orbitals in a shell that contains d-orbitals. There are seven f-orbitals in shells which can contain f-orbitals. Only shells 4 and higher can contain f-orbitals. The shapes of f, g, and other orbitals are more complicated and are really of no importance at this point.

It is usually the case that each new set of orbitals is at a higher potential energy than the last set. In the diagram above all of the shell 3 orbitals are higher than the shell 2 orbitals. One exception in this diagram is the 4s orbital which is lower in energy than the set of 3d orbitals. Since electrons in an atom in the ground state fill the orbitals from the lowest to the highest energy this is an important exception to keep in mind.

Filling Orbitals: the Apartment House Analogy

To figure out where all of the electrons in a ground-state atom are located we can follow the set of rules given in the table below. Next to these rules are some rules that are intended to be similar in spirit. The idea is that filling up the orbitals in the shells of an atom is like renting out apartments in a large building. That is, provided that the superintendent of the building has to follow a very strange set of rules.

The first rule makes a certain amount of sense. Just as you should fill a bookcase from the bottom up, electrons are placed into orbitals from low to high potential energy. The other two rules make a bit more sense only once electron spin is taken into account. Electrons have a quantum property called spin and they are described as either spinning up or down. Electrons that spin in opposite directions may be paired up but electrons that spin in the same direction (we call this parallel spins) may not be paired up. Electrons in an atom have the lowest potential energy when as few electrons are paired up as possible.

Here is an example of the rooms in the apartment house having been filled in by the rules. The element Sulfur has 16 electrons and starting from the bottom up you place two (1 Up and 1 Down) in the 1s orbital.

Next, electrons are placed in each of the 2p orbitals until there is one in each orbital. Then the rest of the electrons are filled into the 2p orbitals. After that the 3s orbital is filled and then the 3p. Electrons are placed in the boxes of the 3p orbitals one at a time until there is one in each orbital. After that the remaining electron is placed as part of a pair in the first 3p box.

One key thing that is of great help with this is that the business with the boxes can be abbreviated the way you see it next to the word Sulfur in the figure at right. The short-hand gives the address of each electron and works like this:

The short-hand notation leaves off the important fact that some electrons in the outermost set of orbitals will prefer to line up with the same spin in separate orbitals. The shorthand notation for the electron configuration of Sulfur is 1s 2 2s 2 2p 6 3s 2 3p 4 . In that notation 1s 2 means principal quantum number 1, s-type orbital, 2 e - ; 2s 2 means principal quantum number 2, s-type orbital, 2 e - ; 2p 6 means principal quantum number 2, p-type orbital, 6 e - and so on.

Connection to Valence Electrons

The valence of an element is the number that governs how many other atoms’ valences it must combine with to make a compound. It is an old-fashioned term for the ‘combining power’ of an element. Elements in the same group (the columns in the periodic table) were originally placed in those groups because they had the same or similar combining powers. You may already know that elements in the same group have the same number of valence electrons. The reason elements in the same column of the periodic table (the so-called Groups) have similar properties is not just because they have the same number of electrons in their valence shell. They have similar properties because their outermost orbitals have the same number of electrons and the same shapes. The inner shells of electrons in an atom are smaller than the outer shells. For this reason, only the outermost shell of electrons can interact with the rest of the world. Since this shell determines the combining power of an element it is called the valence shell .

The electron configurations of Oxygen and Sulfur are given at right. Notice that in both cases the last orbitals to fill are p orbitals. For this reason Oxygen and Sulfur belong to the p-block of elements in the periodic table. Notice also that there are 2 electrons in an s-orbital and 4 electrons in p-orbitals for both Oxygen and Sulfur. In elements in this block of the periodic table the valence electrons include all of those in the outermost s-orbital and p-orbital. All of the elements from Groups 13 to 18 are part of the p-block. All of the elements in this block fill a set of p orbitals last and all of them have their valence electrons in s and p orbitals.

There is a rule in chemistry when it comes to understanding how elements combine. The rule is called the octet rule . The rule states that elements in the s-block and p-block of the periodic table need to have eight electrons in their valence shell in order to be chemically stable. Each s-orbital holds 2 electrons and each p-orbital holds 6 electrons. Together they can hold the eight electrons it takes to finish off the orbitals and make the valence shell full.

Other sections of the periodic table are also known by the type of orbital that fills last in that section. Broadly, this way of looking at the periodic table can explain why it has just the shape that it has. In Groups 1 and 2 the s orbitals are filling. In Groups 3 through 12 the d orbitals are the last to be filled. At a principal quantum number of one (n = 1) there is only an s orbital. At n = 2 there are both s- and p-orbitals available. At n = 3 there are s-, p-, and d-orbitals available. There are no transition metals between Magnesium and Aluminum because the 3d orbitals are higher in energy, and fill up after, the 3p orbitals. Notice that the s-block always precedes the d-block and that the fourth row of the periodic table is where the first d-block elements are found. This is because the 4s orbital is actually slightly lower in energy than the 3d orbitals. (See the diagram on the second page of this packet.) Because they are lower in energy, the 4s, 5s, and 6s orbitals always fill up before the d-orbitals of the previous principal quantum number. In this activity there will not be much concern with any orbitals higher than the 4s orbital since there are some odd exceptions to the orbital-filling order that are beyond the scope of this activity.

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The cabana Club woven bar stool, designed by Richard holbrook, is a synthesis of Casual elegance & sleek geometric lines. The caba . na Club woven bar stool features your choice of tropikane basket or bison weave. Offered in a aluminum frame that can be powder-coated in a range of colors, the cabana Club woven bar stool is perfect for any outdoor social gathering. read more

The cabana Club woven bar stool, designed by Richard holbrook, is a synthesis of Casual elegance & sleek geometric lines. The caba . na Club woven bar stool features your choice of tropikane basket or bison weave. Offered in a aluminum frame that can be powder-coated in a range of colors, the cabana Club woven bar stool is perfect for any outdoor social gathering. read more

The cabana Club woven bar stool, designed by Richard holbrook, is a synthesis of Casual elegance & sleek geometric lines. The caba . na Club woven bar stool features your choice of tropikane basket or bison weave. Offered in a aluminum frame that can be powder-coated in a range of colors, the cabana Club woven bar stool is perfect for any outdoor social gathering. read more

The cabana Club woven bar stool, designed by Richard holbrook, is a synthesis of Casual elegance & sleek geometric lines. The caba . na Club woven bar stool features your choice of tropikane basket or bison weave. Offered in a aluminum frame that can be powder-coated in a range of colors, the cabana Club woven bar stool is perfect for any outdoor social gathering. read more

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Красота на миллион

5 лет гарантии на утюги и парогенераторы

Philips Sonicare - зубная щетка нового поколения

Социальная кампания против рака груди «#ЯПРОШЛА»

Рак молочной железы — это самая распространенная причина смертности от онкологических заболеваний среди женщин и одновременно самый излечимый вид рака. При этом в 94% случаев болезнь можно вылечить, но при одном важном условии — заболевание должно быть обнаружено на ранней стадии.

Смотрите документальный фильм Леонида Парфенова и Катерины Гордеевой «#ЯПРОШЛА».

Philips формирует будущее здравоохранения

Являясь мировым лидером в области здравоохранения, мы руководствуемся принципом того, что в центре нашей повседневной работы всегда находится пациент.

Посетите сайт Philips "Здравоохранение", чтобы узнать больше о последних технологических решениях в области здравоохранения!

Преимущества с клубом Philips

Это – не бритва

В 2017 году Philips устроит революцию, которая перевернёт традиционное представление мужчин о бритье! Попробуй Philips OneBlade!

New Guinea Highlands Coffee Exports was established in 1992 and became a member of the Neumann Kaffe Gruppe in 1996.

We are one of Papua New Guineas leading exporter of coffee.

The companies head office is centrally located in Goroka in the Eastern Highlands Province. We have buying agencies strategically located in all of the major coffee producing areas of Papua New Guinea.

The bulk of coffee that we purchase is milled through our own mill also located in Goroka. This ensures that the coffee meets our strict quality control procedures.

Papua New Guineas Coffee

We have access to all the varieties and grades of coffee produced in Papua New Guinea including Robusta and Arabica as well as Plantation Coffee. We can also supply certified Organic Coffee and Fairtrade Organic.

Our unique supply base, exceptional service and attention to detail have enabled us to be a major supplier of Papua New Guinea Coffee into all the major consuming countries of Papua New Guineas Coffee.

10 – 12 Oct 2018

| Hamburg Messe – Hall A4

Closing Report 2016: Cooperation between COTECA and Kaffee Campus is a complete success

More exhibitors, more visitors, plenty of expert discussions, and a great atmosphere at the stands – the cooperation between COTECA Coffee, Tea and Cocoa Global Industry Expo and the Kaffee Campus of the German Roasters Guild was a complete success.

Nearly 200 exhibitors from 40 nations showcased their products and services for coffee, tea and cocoa at COTECA from 7 to 9 September 2016. Some 3,600 trade visitors came to Hamburg to find out about the products and innovations, and to attend the accompanying presentations and workshops.

Visitors were highly satisfied with the events: 91% praised the quality of information available, 93% highlighted the opportunities for comprehensive expert discussions and exchange of views, and 90% said they were pleased with the very good opportunities to gain and cultivate international contacts.